Saturday, 6 February 2010

Johnald's Fantastical Daily Link Splurge

Johnald's Fantastical Daily Link Splurge

Ultra-Precise Quantum-Logic Clock Puts Old Atomic Clock to Shame

Posted: 05 Feb 2010 03:13 PM PST

Scientists have built a clock which is 100,000 times more precise than the existing international standard.

The quantum-logic clock, which detects the energy state of a single aluminum ion, keeps time to within a second every 3.7 billion years. The new timekeeper could one day improve GPS or detect the slowing of time predicted by Einstein's theory of general relativity.

"It could it be a real contender for the next frequency standard, or next timekeeper," said physicist Chin-wen (James) Chou of the National Institute of Standards and Technology in Boulder, lead author of a study to appear in a forthcoming Physical Review Letters.

Chou's team is one of several racing to build an atomic clock that can replace the current international standard, the cesium fountain clock. The cesium clock loses one second every 100 million years. Chou's is not the first quantum-logic clock, but his uses aluminum and magnesium ions, which makes it twice as precise as its predecessors that used aluminum and beryllium.

To keep time, quantum-logic clocks measure the vibration frequency of UV lasers. Unfortunately, the best lasers we can build veer off their normal frequency by about one tick every hour, Chou said. To keep the laser's timekeeping precise, its vibration must be anchored to something much more stable.

That anchor is the vibration of an electrically charged aluminum atom, which vibrates at 1.1 Petahertz, or 1.1 quadrillion times a second.

The first step in measuring the ion's vibration is to hit it with UV lasers, which are tuned to the charged atom's rate of vibration.The aluminum ion can be in either a low- or high-quantum energy state.

"If the laser frequency is right on the ion frequency, then the ion will change state, but if the laser frequency is off a little bit, then the ion doesn't change state as efficiently," Chou said. "This efficiency is a signal that tells us, this signal is off by so much, and we should steer the frequency so it stays on the frequency of the aluminum ion."

But they can't tune the laser frequency to the aluminum ion state unless they can actually detect that state. To do that, the group couples the aluminum ion to a magnesium ion. A separate set of laser beams shine on the pair. If the aluminum ion changes state, then both ions start to move.

Detecting that motion requires a third set of lasers to focus on the magnesium ion. If the magnesium ion is in motion, it emits a photon of light. Otherwise, it stays dark.

"That's the beauty of it, we can see just one ion emitting light," Chou said.

In a weird twist, the team can't actually tell how many times the clock ticks per second. That's because the definition of a second is currently based on the cesium fountain clock, which simply can't measure the precision of a more precise machine. It works using a similar principle as the aluminum clock, but uses the vibration of a cesium atom to anchor the frequency of a microwave source.

The clock could help resolve questions about the universal physical constants, such as the speed of light in a vacuum, or Planck's constant, an important value in quantum physics.

Physical constants are supposedly fixed over time, but some theories suggest they may vary slightly, he said. "Optical clocks are one of the candidates that might be able to see that really tiny variation over time," he said.

Global positioning devices also rely on extremely precise atomic clocks, so "if we have better and better clocks than we can tell our position, to a better and better precision," Chou said.

And the clocks could also show the effects of general relativity by detecting how much gravity warps time.

There's no plan to adopt the aluminum-ion clock as the formal international standard yet. To do so, the clock ticks need be transmitted around the world. That is normally done with optical cables, but those can only transmit such a stable frequency for around 60 miles, Chou said.

Image: Chou with the quantum clock, J. Burrus/NIST

Citation: C.-W. Chou, D.B. Hume, J.C.J. Koelemeij, D.J. Wineland, and T. Rosenband. C.-W. Chou, D.B. Hume, J.C.J. Koelemeij, D.J. Wineland, and T. Rosenband. 2010. Frequency Comparison of Two High-Accuracy Al+ Optical Clocks. Physical Review Letters.

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Electric Charge Can Change Freezing Point of Water

Posted: 05 Feb 2010 02:03 PM PST


A watched pot never boils, but an electrically charged pot sometimes freezes.

sciencenewsA study in the Feb. 5 Science reports that water can freeze at different temperatures depending on whether the surface it rests on is positively or negatively charged. Under certain conditions, water can even freeze as it heats up.

"We are very, very surprised by this result," says study coauthor Igor Lubomirsky of the Weizmann Institute of Science in Rehovot, Israel. "It means that by controlling surface charge, either positive or negative, you can either suppress ice formation or enhance ice formation."

Water usually begins freezing by forming an ice crystal around a particle of dust or some other impurity. Without that starting point, water can stay liquid well below its freezing point, down to about -42º Celsius. This supercooled water is useful in nature and in the lab, from frogs and fish surviving long winters to cryogenic preservation of blood and tissues.

Scientists have suspected for decades that electric fields could be used to trigger freezing in supercooled water. A molecule of water has a slight positive charge on one end and a negative charge on the other, so electric fields could snap water molecules into a rigid formation by aligning them according to charge.

But previous experiments to understand whether electric fields can influence freezing were complicated by the materials used. The best materials for holding electric charge are metals, but as anyone who has tried to open a car door after a snowstorm knows, ice forms easily on metals even without a charge.

"If you try to do it with metal, you don't know what is from the electric field and what is from the metal itself," Lubomirsky says. "We wanted to know whether it is the charge that does it, or something special in metal."

Instead of metal, Lubomirsky and his colleagues used a pyroelectric material, which can form a short-lived electric field when heated or cooled. The researchers used four pyroelectric crystals, each of which was placed inside a copper cylinder. The bottom surfaces of two crystals were coated with chromium to conduct an electric charge, and the other two were coated with an aluminum oxide to keep the surface uncharged.

The researchers placed the experimental setup in a humid room and turned down the thermostat until water droplets formed on each crystal, then cooled the room further until the water froze.

With no charge on the surface, the water froze at -12.5º C, on average. But on the positively charged surface, water froze at a relatively balmy -7º. And on a negatively charged surface, ice formed, on average, at a chilly -18º.

"It's really dramatic, the strong effect of the charge," says physicist Gene Stanley of Boston University. He also says that the simplicity of the experiment means that "it's the kind of thing that is almost surely correct."

Lubomirsky and colleagues also managed to freeze water by heating it. Water droplets stayed liquid at -11º for up to 10 minutes on a negatively charged surface. But after the negative charge dissipated, heating the room to -8º was enough to induce a positive charge in the pyroelectric crystal and freeze the water.

"That's a very intriguing behavior," comments atmospheric physicist Will Cantrell of Michigan Technological University in Houghton. "In this case, on this particular substance, if you warm it up, you can get it to freeze."

Coauthor Meir Lahav, also of the Weizmann Institute, says water's response to charge probably depends on how the water molecules line up against the surface they're freezing to, though more work is needed to figure out exactly what is happening.

"The water molecules should be aligned differently, so I anticipated that this difference should affect the freezing temperature of ice," Lahav says. "But I didn't expect such a large difference. I'm very much delighted to see that."

Although he has no specific plans to harness the effect for applications such as cryogenic freezing or cloud seeding, Lahav says his team has already filed a patent.

Ice nucleation, "is a very fundamental problem," he says. "The moment you understand better — have a new understanding of a new effect — the applications always come afterwards."

Image: stevendepolo/Flickr

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